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16 July 2021

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EB2023-CMT-019

Oral

Dr. Carlos Lorenzana, Chief Innovation Officer, RIMSA METAL TECHNOLOGY, SA; Dr. Adnan Safraz, Development Manager Automotive, Lapinus; Dr. Andrea Sliepcevich, R&D Manager, Quartz Srl

Detail

The future of Mobility is closely related to the fight against climate change, through the limitation of emissions of all kinds to conclude with the complete electrification of the mobile fleet. In the context of the Green Deal and the objectives of "carbon neutrality" and "zero pollution", the European Commission has committed to reducing current emission limits, from all sources. Brake wear is a significant contributor to respirable particulate matter (PM10 aerodynamic diameter less than 10 µm), particularly in areas with high traffic density and frequent braking. How far emission regulation and electrification may transform the friction industry is still to see. The application of surface technology to the rotor can technically solve this problem and several technologies are being evaluated. But changes in the rotor material induce changes in the response of the friction material, and those can be different depending on the type of friction material and the coating material and technique. In this conference we will be showing some of the changes in tribochemistry and friction response related to the use of coatings, with different carbide coatings. When a hard coating is applied on the rotor, the traditional pad/rotor wear mechanism is affected. The transfer of material from the rotor (in form of iron oxide) is minimized and can even be dismissed. Abrasive wear of the friction material then become the main wear mechanism of the new friction pair. Then the raw materials used in the pad have a big influence on this behaviour. In a joint research work by Rimsa, Quartz and Lapinus, tribological data have been obtained through simulated SAE standard tests by using brake pad screening tribometer, and Tribochemistry was studied by SEM-EDS. We expect to contribute with this work to further build a deep knowledge of how coating parameters may affect the friction behavior of friction materials, allowing the community to find new ways to use more sustainable materials for wear resistant coating.

EuroBrake 2023

Rotor based fundamentals

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From Adhesive wear to Abrasive wear mechanism when switching from conventional rotors to hard coated rotors, EB2023-CMT-019, EuroBrake 2023

EB2022-MDS-024

Oral

Rimsa Metal Technology S.A: Dr. Carlos Lorenzana, Mrs. Gabriela Macías, Mr. Raúl Artal; Quartz Srl: Dr Ruben Beltrami, Mr. Edoardo Cotilli

Detail

Base metals — such as iron ore, copper, aluminium and nickel — are the lifeblood of global industrial production and construction. Shaped by shifts in supply and demand, they are a valuable weathervane of change in the world economy. While attracting less attention than oil prices, metal prices have also been fluctuating strongly since the end of 2003. Metal prices were relatively stable between 1995 and the end of 2003, when demand for metals shifted from advanced economies in the West to emerging markets in the East. The addition of sulfide to the friction material modifies the tribochemistry of the pad/rotor interface, reducing the stick and slip effect, providing a more stable coefficient of friction at high temperatures and reducing the wear. Innovamat is a new Brand born from the collaboration of two well renowned manufacturers of additives for friction materials, Quartz and Rimsa, Rimsa and Quartz, taking advantage of the synergies in between the capabilities of both companies to provide innovative solutions through innovative products to the friction materials industry, and beyond. Our first contribution to those challenges is a comprehensive catalogue of SYNTHETIC SULFIDES designed to replace the LME dependent sulfides, like Tin Sulfides. Discover how our innovative approach to synthetic sulfides contributes to keeping the tribochemistry in the rotor and the pad, providing the same benefit than traditional sulfides based on Tin, Copper or Antimony.

EuroBrake 2022

Poster

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Raw materials strategies for the friction industry to become LME independent in the future, EB2022-MDS-024, EuroBrake 2022

EB2020-FBR-013

Paper + Video + Slides

Detail

Dr. Roberto Dante, Quartz, ITALY

Ing. Edoardo Cotilli, Quartz S.r.l.s.u., ITALY

Ing. Michael Conforti, Quartz S.r.l.s.u., ITALY

Ing. Mario Cotilli, Quartz S.r.l.s.u., ITALY

Ing. John Oleary, Applus IDIADA, UNITED KINGDOM


Antimony trisulfide is widely used in friction materials to stabilize the coefficient of friction in synergy with lubricants and abrasives. It was found that Sb2S3 favors the formation of a steady rotor tribolayer. However, Sb was almost no present in the rotor tribolayer after dynotests, such as the wear test VW TL110, and another test specifically used to collect wear debris, in a low steel formula containing the 5 wt% of Sb2S3 . Indeed, in wear debris Sb, as well as on the rotor surface, was actually found as sulfide Sb2S3 and even as metallic antimony. It seems that Sb2S3 decomposes to metallic antimony, as supported also by previous thermal gravimetric and scanning calorimetry studies, which sublimates due to the high contact temperatures achieved during the braking applications skipping the stage of oxide formation. In contact asperities the concept of temperature can be used only with approximation, since reactions and transformations under friction are activated by friction work (which breaks bonds) rather than only direct heat, and follow different pathways from those occurring in standard thermal chemistry. Apart as working as a coadjuvant of lubricants for its ability to create a steady tribolayer, the mechanism of action of Sb2S3 seems to be linked to sublimation as a metal from the tribolayer and wera debris. These facts open a new sight on the mechanism of action of this common ingredient of friction materials. The performance of antimony trisulfide, which provides a steady coefficient of friction and tribolayer, seems to be linked to its instability. The deepening in its peculiar tribochemistry and tribophysics can help to develop valid alternatives.

EuroBrake 2021

EFF

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Wear Debris Emissions and Antimony Trisulfide Tribochemistry, EB2020-FBR-013, EuroBrake 2021
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